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E. V. Trofimova, T. E. Gulov, A. N. Fedotov, S. G. Bandaev, S. S. Mochalov

Benzylcyclopropane in reaction solvomercuration


Benzylcyclopropanes regioselectively react with mercury (II) acetate in formic acid to give mercursolvoadducts with high yields. It was shown that formyloxygroup in homobenzyl position of 4-chloromercursubstituted arylbutanes is predisposed to easy solvolysis or nucleofilic substitution for bromine under bromodemercuration conditions.
Moscow University Chemistry Bulletin.
2012, Vol. 53, No. 3, P. 181

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