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A. Kh. Vorobiev, V. S. Gurman, Y. B. Kheyfets

Photochemical dissociation of the 2,2,5,5-tetramethyl-4-phenyl-3-imidazoline -1-oxide


The photochemical dissociation of the 2,2,5,5-tetramethyl-4-phenyl-3-imidazoline -1-oxide was investigated in solution and in solid matrixes. It was found out that elimination of the nitrogen oxide is occurred during the reaction. Quantum yield is equal to ~0,2 at 298 K and ~0.001 at 77 K. Reaction kinetics in solid matrixes is stepped.
Moscow University Chemistry Bulletin.
2008, Vol. 49, No. 1, P. 7

Copyright (C) Chemistry Dept., Moscow State University, 2002
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