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D. Yu. Kultin, A. V. Ivanov, O. K. Lebedeva, L. M. Kustov

Electrochemical syntheses of polyphenilethylens in room-temperature ionic liquids

Abstract

Electrochemical oxidation of benzene in room-temperature ionic liquids on the base of complex N - butylpyridiniumchloride and AlCl3 ([PyBuCl]Al2Cl6) under controlling potential on platinum and glassycarbon composite (GlC) electrodes electrodes was studied. Linear polymers (degree of polymerization was 8  120) were obtained as products. It was shown that the degree of polymerization is increasing in according with electrodes potential. The characterization of reaction products was performed using FTIR spectroscopy.
Moscow University Chemistry Bulletin.
2002, Vol. 43, No. 3, P. 178
   

Copyright (C) Chemistry Dept., Moscow State University, 2002
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